| Publication Type |
Journal Article |
| Title |
Supramolecular arrangement promoted in trans-[PdCl2(HONC10H14O)(2)]center dot 2H(2)O by hydrogen bonding |
| Authors |
Adelino M. Galvão M Fernanda NN Carvalho Antonio L. Grilo |
| Groups |
BIOMOL |
| Journal |
JOURNAL OF MOLECULAR STRUCTURE |
| Year |
2014 |
| Month |
May |
| Volume |
1065 |
| Number |
|
| Pages |
108-112 |
| Abstract |
Palladium(II) complexes trans-[PdCl2(3-HONC10H14O)(2)]center dot 2H(2)O and trans-[PdCl2(2-HONC10H16)(2)] with similar formulations and molecular geometries display considerably different supramolecular arrangements due to hydrogen bonding involving the oxime substituent (NOH) of the camphor ligand, the halide co-ligand of adjacent molecules and H2O outer-sphere molecules in the case of trans-[PdCl2(3-HONC10H14 O)(2)]center dot 2H(2)O. The discussion is based on data collected by X-ray diffraction analysis and DFT calculations. (C) 2014 Elsevier B.V. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/j.molstruc.2014.02.054 |
| ISBN |
|
| Publisher |
ELSEVIER SCIENCE BV |
| Book Title |
|
| ISSN |
0022-2860 |
| EISSN |
1872-8014 |
| Conference Name |
|
| Bibtex ID |
ISI:000335806200015 |
| Observations |
|