Publication Type Journal Article
Title Supramolecular arrangement promoted in trans-[PdCl2(HONC10H14O)(2)]center dot 2H(2)O by hydrogen bonding
Authors Adelino M. Galvão M Fernanda NN Carvalho Antonio L. Grilo
Groups BIOMOL
Journal JOURNAL OF MOLECULAR STRUCTURE
Year 2014
Month May
Volume 1065
Number
Pages 108-112
Abstract Palladium(II) complexes trans-[PdCl2(3-HONC10H14O)(2)]center dot 2H(2)O and trans-[PdCl2(2-HONC10H16)(2)] with similar formulations and molecular geometries display considerably different supramolecular arrangements due to hydrogen bonding involving the oxime substituent (NOH) of the camphor ligand, the halide co-ligand of adjacent molecules and H2O outer-sphere molecules in the case of trans-[PdCl2(3-HONC10H14 O)(2)]center dot 2H(2)O. The discussion is based on data collected by X-ray diffraction analysis and DFT calculations. (C) 2014 Elsevier B.V. All rights reserved.
DOI http://dx.doi.org/10.1016/j.molstruc.2014.02.054
ISBN
Publisher ELSEVIER SCIENCE BV
Book Title
ISSN 0022-2860
EISSN 1872-8014
Conference Name
Bibtex ID ISI:000335806200015
Observations
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