| Publication Type |
Journal Article |
| Title |
SELECTIVE HYDRATION OF FERROCENYLETHYNE MEDIATED BY A PALLADIUM COMPLEX WITH A CAMPHORHYDRAZONE LIGAND |
| Authors |
Jiri Tauchman M Fernanda NN Carvalho Petr Stepnicka |
| Groups |
BIOMOL |
| Journal |
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS |
| Year |
2011 |
| Month |
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|
| Volume |
76 |
| Number |
11 |
| Pages |
1277-1283 |
| Abstract |
Complex [PdCl2L2], where L is a camphor hydrazone ligand, (1R, 4S)-1,7,7-trimethyl-3-( 2,2-dimethylhydrazone)-bicyclo[2.2.1]heptane-2,3-dione, efficiently promotes Markovnikov hydration of ethynylferrocene to acetylferrocene in aqueous methanol at room temperature. 1-Ferrocenylprop-1-yne and simple organic alkynes such as 1-octyne or ethynylbenzenes are not affected or polymerize under the reaction conditions. |
| DOI |
http://dx.doi.org/10.1135/cccc2011130 |
| ISBN |
|
| Publisher |
INST ORGANIC CHEM AND BIOCHEM |
| Book Title |
|
| ISSN |
0010-0765 |
| EISSN |
1212-6950 |
| Conference Name |
|
| Bibtex ID |
ISI:000298004700001 |
| Observations |
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