| Publication Type |
Journal Article |
| Title |
Murai Reaction on Furfural Derivatives Enabled by Removable N,N -Bidentate Directing Groups |
| Authors |
Cristofer Pezzetta Luis F. Veiros Julie Oble Giovanni Poli |
| Groups |
IOARC |
| Journal |
CHEMISTRY-A EUROPEAN JOURNAL |
| Year |
2017 |
| Month |
June |
| Volume |
23 |
| Number |
35 |
| Pages |
8385-8389 |
| Abstract |
Furfural and related compounds are industrially relevant building blocks obtained from lignocellulosic biomass. To enhance the added value of these renewable resources, a Ru-catalyzed hydrofurylation of alkenes, involving a directed C-H activation at C3 of the furan ring, was developed. A thorough experimental study revealed that a bidentate amino-imine directing group enabled the desired coupling. Removal of the directing group occurred during the purification step, directly releasing the C3-functionalized furfurals. Development of the reaction as well as optimization and scope of the method were described. A mechanism was proposed on the basis of DFT calculations. |
| DOI |
http://dx.doi.org/10.1002/chem.201701850 |
| ISBN |
|
| Publisher |
WILEY-V C H VERLAG GMBH |
| Book Title |
|
| ISSN |
0947-6539 |
| EISSN |
1521-3765 |
| Conference Name |
|
| Bibtex ID |
ISI:000404009500010 |
| Observations |
|
