| Publication Type |
Journal Article |
| Title |
Molecular switching through cooperative ionic interactions and charge assisted hydrogen bonding |
| Authors |
Atash V. Gurbanov Kamran T. Mahmudov Maximilian N. Kopylovich M. Fátima C. Guedes da Silva Manas Sutradhar Firudin I. Guseinov Fedor I. Zubkov Abel M. Maharramov Armando J.L. Pombeiro |
| Groups |
CCC |
| Journal |
DYES AND PIGMENTS |
| Year |
2017 |
| Month |
March |
| Volume |
138 |
| Number |
|
| Pages |
107-111 |
| Abstract |
Sodium 2-(2-(1-cyano-2-oxopropylidene)hydrazinyl)benzenesulfonate (NaHL) was synthesized by azocoupling of diazonium salt of 2-aminobenzenesulfonic acid with 3-oxobutanenitrile and characterized by and C-13 NMR spectroscopies and ESI-MS analysis. In dimethylsulfoxide-d6 solution NaHL exists as a mixture of Z- and E-hydrazone forms in the amounts of 96 and 4\%, respectively. Treatment of this isomeric mixture with copper(II) nitrate hydrate in the presence of ethylenediamine (en) provides unusual (E,Z) -> E switching of NaHL to give [Cu(H2O)(2)(en)(2)](HL)(2) (1). The process is interpreted on the basis of cooperative ionic interactions and resonance assisted hydrogen bonding (RAHB) -> charge assisted hydrogen bonding (CAHB) transition. (C) 2016 Elsevier Ltd. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/j.dyepig.2016.11.029 |
| ISBN |
|
| Publisher |
ELSEVIER SCI LTD |
| Book Title |
|
| ISSN |
0143-7208 |
| EISSN |
1873-3743 |
| Conference Name |
|
| Bibtex ID |
ISI:000392681700014 |
| Observations |
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