| Publication Type |
Journal Article |
| Title |
A New Post-Metallocene-Ti Catalyst with Maltolate Bidentade Ligand: an Investigation in Heterogeneous Polymerization Reactions in Different Mesoporous Supports |
| Authors |
Grasiela Gheno Nara Regina de Souza Basso Paolo Roberto Livotto M R Ribeiro João P. Lourenço Ana Elisa Ferreira Griselda Barrera Galland |
| Groups |
CATHPRO |
| Journal |
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY |
| Year |
2016 |
| Month |
November |
| Volume |
27 |
| Number |
11 |
| Pages |
2082-2092 |
| Abstract |
A new titanium catalyst easily synthesized from ethylmaltol bidentate chelator ligand was studied in homogeneous and heterogeneous ethylene polymerization. The dichlorobis(3-hydroxy-2-ethyl-4-pyrone) titanium(IV) complex was characterized by H-1 and C-13 NMR (nuclear magnetic resonance), UV-Vis and elemental analysis. Theoretical study by density functional theory (DFT) showed that the complex chlorines exhibit cis configuration, which is important for the activity in olefin polymerization. The complex was supported by two methods, direct impregnation or methylaluminoxane (MAO) pre-treatment, in five mesoporous supports: MCM-41 (micro and nano), SBA-15 and also the corresponding modified Al species. All the catalytic systems were active in ethylene polymerization and the catalytic activity was strongly influenced by the method of immobilization of the catalyst and the type of support. |
| DOI |
http://dx.doi.org/10.5935/0103-5053.20160099 |
| ISBN |
|
| Publisher |
SOC BRASILEIRA QUIMICA |
| Book Title |
|
| ISSN |
0103-5053 |
| EISSN |
1678-4790 |
| Conference Name |
|
| Bibtex ID |
ISI:000388444900018 |
| Observations |
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