| Publication Type |
Journal Article |
| Title |
Solubilities of C-Tetraalkylcalix[4]resorcinarenes in SCCO2: Experimental Measurements, Characterization, and Correlation |
| Authors |
José Coelho Greta P. Naydenova Stoyan M. Miloshev Christo P. Novakov Pavlina P. Petrova Dragomir S. Yankov Roumiana Stateva |
| Groups |
MET |
| Journal |
JOURNAL OF CHEMICAL AND ENGINEERING DATA |
| Year |
2015 |
| Month |
March |
| Volume |
60 |
| Number |
3 |
| Pages |
909-918 |
| Abstract |
The solubilities of two C-tetraalkylcalix[4]resorcinarenes, namely C-tetramethylcalix[4]resorcinarene and C-tetrapentylcalix[4]resorcinarene, in supercritical carbon dioxide (SCCO2) were measured in a flow-type apparatus at a temperature range from (313.2 to 333.2) K and at pressures from (12.0 to 35.0) MPa. The C-tetraalkylcalix[4]resorcinarenes were synthesized applying our optimized procedure and fully characterized by means of gel permeation chromatography, infrared and nuclear magnetic resonance spectroscopy. The solubilities of the C-tetraalkylcalix[4]resorcinarenes in SCCO2 were determined by analysis of the extracts obtained by HPLC with ultraviolet (UV) detection methodology adapted by our team. Four semiempirical density-based models, and the SoaveRedlichKwong cubic equation of state (SRK CEoS) with classical mixing rules, were applied to correlate the solubility of the calix[4]resorcinarenes in the SC CO2. The physical properties required for the modeling were estimated and reported. |
| DOI |
http://dx.doi.org/10.1021/je500990f |
| ISBN |
|
| Publisher |
AMER CHEMICAL SOC |
| Book Title |
|
| ISSN |
0021-9568 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000351186600058 |
| Observations |
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