| Publication Type |
Journal Article |
| Title |
Trienamines derived from 5-substituted furfurals: remote epsilon-functionalization of 2,4-dienals |
| Authors |
Jaime A. S. Coelho Alexandre F. Trindade Vânia André M. Teresa Duarte Luis F. Veiros Carlos A. M. Afonso |
| Groups |
BIOMOL IOARC |
| Journal |
ORGANIC \& BIOMOLECULAR CHEMISTRY |
| Year |
2014 |
| Month |
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|
| Volume |
12 |
| Number |
46 |
| Pages |
9324-9328 |
| Abstract |
The selective epsilon-functionalization of 5-substituted furfurals via trienamine intermediates is reported herein. This methodology was successfully applied to several 5-substituted furfurals with different amines via formation of a trienamine through the furan ring. The rationalized reaction mechanism involves the addition of the trienamine intermediate to its corresponding iminium-ion producing new furan-containing scaffolds. |
| DOI |
http://dx.doi.org/10.1039/c4ob01759e |
| ISBN |
|
| Publisher |
ROYAL SOC CHEMISTRY |
| Book Title |
|
| ISSN |
1477-0520 |
| EISSN |
1477-0539 |
| Conference Name |
|
| Bibtex ID |
ISI:000344989700004 |
| Observations |
|
