Publication Type |
Journal Article |
Title |
Regioselective C-C bond cleavage in arylhydrazones of 4,4,4-trifluoro-1-(thiophen-2-yl)butane-1,3-diones |
Authors |
Reza Solhnejad Farciana S. Aliyeva Abel M. Maharramov Rafiga A. Aliyeva Famil M. Chyragov Atash V. Gurbanov Kamran T. Mahmudov Maximilian N. Kopylovich |
Groups |
CCC |
Journal |
JOURNAL OF MOLECULAR STRUCTURE |
Year |
2013 |
Month |
October |
Volume |
1050 |
Number |
|
Pages |
180-184 |
Abstract |
New (Z)-2-(2-(para-substituted phenyl)hydrazono)-4,4,4-trifluoro-1-(thiophen-2-yl)butane-1,3-diones with chloro (1), bromo (2) and carboxy (3) substituents were synthesized and characterized by ESI-MS, IR, H-1 and C-13 NMR spectroscopies and elemental analysis. The regioselective carbon-carbon bond cleavage with the formation (E)-2-(2-(4-substituted phenyl) hydrazono)-1-(thiophen-2-yl)ethanones was achieved upon heating (80 degrees C) of 1-3 in methanol-water. Crown Copyright (C) 2013 Published by Elsevier B.V. All rights reserved. |
DOI |
http://dx.doi.org/10.1016/j.molstruc.2013.07.035 |
ISBN |
|
Publisher |
|
Book Title |
|
ISSN |
0022-2860 |
EISSN |
1872-8014 |
Conference Name |
|
Bibtex ID |
ISI:000326007200027 |
Observations |
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