Publication Type Journal Article
Title Regioselective C-C bond cleavage in arylhydrazones of 4,4,4-trifluoro-1-(thiophen-2-yl)butane-1,3-diones
Authors Reza Solhnejad Farciana S. Aliyeva Abel M. Maharramov Rafiga A. Aliyeva Famil M. Chyragov Atash V. Gurbanov Kamran T. Mahmudov Maximilian N. Kopylovich
Groups CCC
Journal JOURNAL OF MOLECULAR STRUCTURE
Year 2013
Month October
Volume 1050
Number
Pages 180-184
Abstract New (Z)-2-(2-(para-substituted phenyl)hydrazono)-4,4,4-trifluoro-1-(thiophen-2-yl)butane-1,3-diones with chloro (1), bromo (2) and carboxy (3) substituents were synthesized and characterized by ESI-MS, IR, H-1 and C-13 NMR spectroscopies and elemental analysis. The regioselective carbon-carbon bond cleavage with the formation (E)-2-(2-(4-substituted phenyl) hydrazono)-1-(thiophen-2-yl)ethanones was achieved upon heating (80 degrees C) of 1-3 in methanol-water. Crown Copyright (C) 2013 Published by Elsevier B.V. All rights reserved.
DOI http://dx.doi.org/10.1016/j.molstruc.2013.07.035
ISBN
Publisher
Book Title
ISSN 0022-2860
EISSN 1872-8014
Conference Name
Bibtex ID ISI:000326007200027
Observations
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