| Publication Type |
Journal Article |
| Title |
Benzo[c]thiophene Chromophores Linked to Cationic Fe and Ru Derivatives for NLO Materials: Synthesis Characterization and Quadratic Hyperpolarizabilities |
| Authors |
Tiago J. L. Silva Paulo Mendes M. Helena Garcia M Paula Robalo Joao P. Prates Ramalho A. J. Palace Carvalho Marina Buechert Christian Wittenburg Juergen Heck |
| Groups |
BIOIN BIOMOL |
| Journal |
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY |
| Year |
2013 |
| Month |
July |
| Volume |
2013 |
| Number |
20 |
| Pages |
3506-3517 |
| Abstract |
5-Monocyclopentadienyliron(II)/ruthenium(II) complexes of the general formula [M(5-C5H5)(PP)(L1)][PF6] \M = Fe, PP = dppe; M = Ru, PP = dppe or 2PPh3; L1 = 5-[3-(thiophen-2-yl)benzo[c]thiophenyl]thiophene-2-carbonitrile\ have been synthesized and studied to evaluate their molecular quadratic hyperpolarizabilities. The compounds were fully characterized by NMR, FTIR and UV/Vis spectroscopy and their electrochemical behaviour studied by cyclic voltammetry. Quadratic hyperpolarizabilities () were determined by hyper-Rayleigh scattering measurements at a fundamental wavelength of 1500 nm. Density functional theory calculations were employed to rationalize the second-order non-linear optical properties of these complexes. |
| DOI |
http://dx.doi.org/10.1002/ejic.201300048 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
1434-1948 |
| EISSN |
1099-0682 |
| Conference Name |
|
| Bibtex ID |
ISI:000325917100012 |
| Observations |
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