| Publication Type |
Journal Article |
| Title |
1D Cu(II) coordination polymer derived from 2-(2-(2,4-dioxopentan-3-ylidene) hydrazinyl)benzenesulfonate chelator and pyrazine spacer |
| Authors |
Kamran T. Mahmudov Matti Haukka Manas Sutradhar Archana Mizar Maximilian N. Kopylovich Armando J.L. Pombeiro |
| Groups |
CCC |
| Journal |
JOURNAL OF MOLECULAR STRUCTURE |
| Year |
2013 |
| Month |
February |
| Volume |
1033 |
| Number |
|
| Pages |
127-130 |
| Abstract |
Reaction of 2-(2-(2,4-dioxopentan-3-ylidene)hydrazinyl)benzenesulfonic acid (H2L) with copper(II) nitrate hydrate in the presence of pyrazine (pz) in methanol affords the coordination polymer [Cu-2(mu-L)(2)(H2O)(2)(mu-pz)](n) (1), where the bidentate pz molecule links two Cu(II) centres of two different dimeric units, giving rise to a one-dimensional chain. The dimeric unit [Cu-2(mu-L)(2)(H2O)(2)] consists of two distorted octahedral Cu(II) centres connected via oxygen atoms of the sulfo group of the bridging L2- ligand. The extensive hydrogen bonding between the coordinated water and pz molecules leads to the formation of a supramolecular 3D associate. Compound 1 has been characterized by elemental analysis, ESI-MS, IR spectroscopy and single-crystal X-ray diffraction analysis. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/j.molstruc.2012.08.012 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
0022-2860 |
| EISSN |
|
| Conference Name |
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| Bibtex ID |
ISI:000312965800019 |
| Observations |
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