| Publication Type |
Journal Article |
| Title |
Cyclam Functionalization through Isocyanate Insertion in Zr-N Bonds |
| Authors |
Luis G. Alves Ana M. Martins |
| Groups |
IOARC |
| Journal |
INORGANIC CHEMISTRY |
| Year |
2012 |
| Month |
January |
| Volume |
51 |
| Number |
1 |
| Pages |
10-12 |
| Abstract |
The insertion of isocyanates in (Bn(2)Cyclam)ZrX2 is regioselective; (Bn(2)Cyclam)Zr(OR)(2) produces urea-like moieties by the insertion of RN=C=O in the Zr-N-amido bonds of the cyclam ring. Depending on the bulkiness of the isocyanate R groups, O- and N-bound ureates are formed. (Bn(2)Cyclam)Zr((NHBu)-Bu-t)(2) reacts with MesN=C=O at the terminal Zr-N bonds. |
| DOI |
http://dx.doi.org/10.1021/ic201750y |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
0020-1669 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000298712000004 |
| Observations |
|
