| Publication Type |
Journal Article |
| Title |
Solvent Effects on the Coexistence of Localized and Delocalized 4,4 -Dinitrotolane Radical Anion by Resonance Raman Spectroscopy |
| Authors |
Ryan M. Hoekstra J. P. Telo Qin Wu Rachel M. Stephenson Stephen F. Nelsen Jeffrey I. Zink |
| Groups |
BIOMOL |
| Journal |
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY |
| Year |
2010 |
| Month |
July |
| Volume |
132 |
| Number |
26 |
| Pages |
8825+ |
| Abstract |
The resonance Raman spectrum of the simple alkyne bndge in 4,4 -dimtrotolane radical anion shows two distinct bands, providing proof of the solvent-dependent coexistence of charge-localized and -delocalized species. The Raman spectra of normal modes primarily involving the charge-bearing -PhNO(2) units also support the coexistence of two solvent-dependent electronic species. The temperature dependence of the spectra of the bridging unit shows an inverse relationship between the solvent reorganization energy (lambda(s)) and the temperature. |
| DOI |
http://dx.doi.org/10.1021/ja1017859 |
| ISBN |
|
| Publisher |
AMER CHEMICAL SOC |
| Book Title |
|
| ISSN |
0002-7863 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000279561200007 |
| Observations |
|
