| Publication Type |
Journal Article |
| Title |
Water-soluble and stable dinitrogen phosphine complexes trans-[ReCl(N-2)(PTA-H)(n)(PTA)(4-n)](n+) (n=0-4), the first with 1,3,5-triaza-7-phosphaadamantane |
| Authors |
P. Smolenski Armando J.L. Pombeiro |
| Groups |
CCC |
| Journal |
DALTON TRANSACTIONS |
| Year |
2008 |
| Month |
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|
| Volume |
|
| Number |
1 |
| Pages |
87-91 |
| Abstract |
The first dinitrogen complexes with the hydrosoluble PTA ligand, or its protonated form PTA-H, trans-[ReCl(N-2)(PTA-H) n(PTA)(4-n)](n+) (n = 0-4), are prepared, shown to be soluble and stable in water, interconvertible by stepwise protonation/deprotonation and to form, upon N-2 loss, the corresponding penta-coordinate compounds. Dinitrogen displacement by CO affords trans-[ReCl(CO)(PTA)(4)]. |
| DOI |
http://dx.doi.org/10.1039/b712360d |
| ISBN |
|
| Publisher |
ROYAL SOC CHEMISTRY |
| Book Title |
|
| ISSN |
1477-9226 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000251673200015 |
| Observations |
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