| Publication Type |
Journal Article |
| Title |
Chlorobis(dimethylamido)(eta(5)-2,5-dimethylpyrrolyl)titanium(IV), [Ti(NMe2)(2)(DMP)Cl] |
| Authors |
M. Teresa Duarte A Ferreira A. R. Dias MM Salema JF da Silva |
| Groups |
|
| Journal |
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS |
| Year |
2005 |
| Month |
February |
| Volume |
61 |
| Number |
2 |
| Pages |
M104-M106 |
| Abstract |
The structure of the title compound, [Ti(C2H6N)(2)(C6H8N)Cl], displays a eta(5)-coordination mode for the pyrrolyl ring, confirmed by the values of the slip parameter [0.073 (9) Angstrom] and the fold angle [4.6 (6)degrees]. This coordination is confirmed by NMR data, which point to the involvement of the complex in a fluxional process in solution above 285 K, passing through an intermediate involving simultaneously a metal-azaallyl and a metal-olefin bond. |
| DOI |
http://dx.doi.org/10.1107/S0108270104031695 |
| ISBN |
|
| Publisher |
WILEY-BLACKWELL |
| Book Title |
|
| ISSN |
0108-2701 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000227376600021 |
| Observations |
|
