Publication Type Journal Article
Title Synthesis and crystal structure of the novel trimanganese tetrathiolate incomplete cubane: [Mo(eta(5)-C5H5)(2)(H)CO][Mn-3(CO)(9)(mu-SC6H5)(4)]
Authors A. R. Dias Adelino M. Galvão M. Helena Garcia Maria J. Villa de Brito
Groups
Journal JOURNAL OF ORGANOMETALLIC CHEMISTRY
Year 2001
Month February
Volume 620
Number 1
Pages 276-281
Abstract An unexpected trimanganese(I) tetrathiolate-bridged complex, [Mn-3(CO)(9)(mu -SC6H5)(4)](-), with an incomplete cubane structure, was obtained by thermal reaction of [Mn-2(CO)(10)] with [Mo(eta (5)-C5H5)(2)(SC6H5)(2)]. The structure, established by single-crystal X-ray diffraction studies, shows the cation, [Mo(eta (5)-C(5)H5)(2)(H)CO](+), directed towards the vacant site of the cubane structure. Possible routes by which the anion and the cation could be formed are discussed. (C) 2001 Elsevier Science B.V. All rights reserved.
DOI http://dx.doi.org/10.1016/S0022-328X(00)00798-1
ISBN
Publisher ELSEVIER SCIENCE SA
Book Title
ISSN 0022-328X
EISSN
Conference Name
Bibtex ID ISI:000167246400032
Observations
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