| Publication Type |
Journal Article |
| Title |
Structural characterisation of flavonoids and flavonoid-O-glycosides extracted from Genista tenera by fast-atom bombardment tandem mass spectrometry |
| Authors |
Carlos M. Borges P Martinho Alice Martins Amélia P. Rauter MAA Ferreira |
| Groups |
HC |
| Journal |
RAPID COMMUNICATIONS IN MASS SPECTROMETRY |
| Year |
2001 |
| Month |
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|
| Volume |
15 |
| Number |
18 |
| Pages |
1760-1767 |
| Abstract |
Genista tenera is a plant native to the Madeira Island (Portugal). From the ethanol extract of its powdered aerial parts, two flavones, three isoflavones and one 7-O-glacosyl isoflavone were isolated. A mass spectrometric study of these compounds was performed using liquid secondary ion mass spectrometry (LSIMS) in combination with high-energy collision-induced dissociation (CID) and tandem mass spectrometry (MS/MS). Characteristic fragmentation patterns were observed in all the investigated compounds; the loss of small neutral species from the protonated molecules was useful for identifying the presence of specific functional groups in the A- and B-rings. In order to help to establish the proposed structures, NMR and UV studies were also performed. Copyright (C) 2001 John Wiley \& Sons, Ltd. |
| DOI |
http://dx.doi.org/10.1002/rcm.436 |
| ISBN |
|
| Publisher |
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| Book Title |
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| ISSN |
0951-4198 |
| EISSN |
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| Conference Name |
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| Bibtex ID |
ISI:000171017900016 |
| Observations |
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