Publication Type Journal Article
Title Conducting polymers with attached platinum nanoparticles towards the development of DNA biosensors
Authors V. C. Ferreira A. I. Melato A. F. Silva L. M. Abrantes
Groups
Journal ELECTROCHEMISTRY COMMUNICATIONS
Year 2011
Month September
Volume 13
Number 9
Pages 993-996
Abstract Based on the strong interaction of noble metal particles with the sulphur atoms of thiophene derivatives, platinum nanoparticles (Pt-NPs)-dispersed poly(3-methylthiophene) (P\3-MeTh\) thin films have been successfully prepared. Evidence of the Pt-NPs confinement in the polymer was provided by the electrocatalytic activity of the modified electrodes towards the dissolved oxygen reduction reaction. The efficient immobilization by self-assembly of thiolated oligonucleotides on the embedded Pt-NPs could be monitored by electrochemical quartz crystal microbalance (EQCM) as well as the subsequent hybridization with the complementary sequence. The good conducting properties and high surface area of P(3-MeTh)/Pt-NPs modified electrodes also allowed the detection of both processes by cyclic voltammetry. (C) 2011 Elsevier B.V. All rights reserved.
DOI http://dx.doi.org/10.1016/j.elecom.2011.06.021
ISBN
Publisher
Book Title
ISSN 1388-2481
EISSN
Conference Name
Bibtex ID ISI:000294940600026
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