| Publication Type |
Journal Article |
| Title |
Oxidation of saturated hydrocarbons to alkyl hydroperoxides by a H2O2/titanosilicalite-1/NaOH/MeCN system |
| Authors |
Georgiy B. Shul'pin M Kirillova Tawan Sooknoi Armando J.L. Pombeiro |
| Groups |
BIOMOL CCC |
| Journal |
CATALYSIS LETTERS |
| Year |
2008 |
| Month |
June |
| Volume |
123 |
| Number |
1 |
| Pages |
135-141 |
| Abstract |
Hydrogen peroxide oxidizes alkanes at room temperature to produce the corresponding alkyl hydroperoxides in the presence of titanosilicalite-1, NaOH and acetonitrile. The reaction proceeds with low regio- and bond-selectivity and its mechanism apparently involves the formation of hydroxyl radicals. |
| DOI |
http://dx.doi.org/10.1007/s10562-008-9406-8 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
1011-372X |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000256081700021 |
| Observations |
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