| Publication Type |
Journal Article |
| Title |
Accessing Two-Coordinate Zn-II Organocations by NHC Coordination: Synthesis, Structure, and Use as pi-Lewis Acids in Alkene, Alkyne, and CO2 Hydrosilylation |
| Authors |
David Specklin Frederic Hild Christophe Fliedel Christophe Gourlaouen Luis F. Veiros Samuel Dagorne |
| Groups |
IOARC |
| Journal |
CHEMISTRY-A EUROPEAN JOURNAL |
| Year |
2017 |
| Month |
November |
| Volume |
23 |
| Number |
63 |
| Pages |
15908-15912 |
| Abstract |
Discrete two-coordinate Zn-II organocations of the type (NHC)Zn-R+ are reported, thanks to NHC stabilization. In preliminary reactivity studies, such entities, which are direct cationic analogues of long-known ZnR2 species, act as effective and tunable pi-Lewis acid catalysts in alkene, alkyne, and CO2 hydrosilylation. |
| DOI |
http://dx.doi.org/10.1002/chem.201704382 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
0947-6539 |
| EISSN |
1521-3765 |
| Conference Name |
|
| Bibtex ID |
ISI:000414990400012 |
| Observations |
|
