| Publication Type |
Journal Article |
| Title |
Synthesis, structure and solution behaviour of U(III) poly(3,5-diisopropylpyrazoly)borate complexes |
| Authors |
Leonor Maria A Domingos Isabel Santos |
| Groups |
IOARC |
| Journal |
INORGANIC CHEMISTRY COMMUNICATIONS |
| Year |
2003 |
| Month |
January |
| Volume |
6 |
| Number |
1 |
| Pages |
58-60 |
| Abstract |
The novel KBp(iPr2) and the previously described KTp(iPr2) react with [UI3(THF)(4)], in THF, yielding the new compounds [U \kappa(3)-Bp(iPr2))\(3)] (1) and [UI2 (kappa(3)-Tp(iPr2))(THF)(x)] (x = 2-3) (2), respectively. Compound 1 is remarkably stable, while 2 decomposes in solution, being the main decomposition product [UI2 (kappa(3)-Tp(iPr2)) (kappa(1)-Tp(iPr2)H)] (3). The formation of 3 is prevented when [UI3(THF)(4)] reacts with KTp(iPr2) in toluene, in the presence of strong neutral coordinating ligands. (C) 2002 Elsevier Science B.V. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/S1387-7003(02)00681-0 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
1387-7003 |
| EISSN |
1879-0259 |
| Conference Name |
|
| Bibtex ID |
ISI:000180272000015 |
| Observations |
|