Publication Type Journal Article
Title Synthesis, structure and solution behaviour of U(III) poly(3,5-diisopropylpyrazoly)borate complexes
Authors Leonor Maria A Domingos Isabel Santos
Groups IOARC
Journal INORGANIC CHEMISTRY COMMUNICATIONS
Year 2003
Month January
Volume 6
Number 1
Pages 58-60
Abstract The novel KBp(iPr2) and the previously described KTp(iPr2) react with [UI3(THF)(4)], in THF, yielding the new compounds [U \kappa(3)-Bp(iPr2))\(3)] (1) and [UI2 (kappa(3)-Tp(iPr2))(THF)(x)] (x = 2-3) (2), respectively. Compound 1 is remarkably stable, while 2 decomposes in solution, being the main decomposition product [UI2 (kappa(3)-Tp(iPr2)) (kappa(1)-Tp(iPr2)H)] (3). The formation of 3 is prevented when [UI3(THF)(4)] reacts with KTp(iPr2) in toluene, in the presence of strong neutral coordinating ligands. (C) 2002 Elsevier Science B.V. All rights reserved.
DOI http://dx.doi.org/10.1016/S1387-7003(02)00681-0
ISBN
Publisher
Book Title
ISSN 1387-7003
EISSN 1879-0259
Conference Name
Bibtex ID ISI:000180272000015
Observations
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