Publication Type Journal Article
Title Unique uranium(III) cations anchored by polydentate sulfur-based ligands: Synthesis and structure of [U\ H(R)B(tim(Me))(2)\(2)(THF)(3)][BPh4] (R = H, Ph)
Authors Leonor Maria A Domingos Isabel Santos
Groups IOARC
Journal INORGANIC CHEMISTRY
Year 2001
Month December
Volume 40
Number 27
Pages 6863+
Abstract The reactions of bis(2-mercapto- 1 -methylimidazolyl)-borates ([H(R)B(tim(Me))(2)](-), R = H and Ph) with [UI3-(THF)(4)] and TI[BPh4] in tetrahydrofuran gave, in good yield, [U\H(R)B(tim(Me))(2)\(2)(THF)(3)][BPh4] (R = H (1), R = Ph (2)), Complexes I and 2 are rare examples of U(III)) cations and unprecedented examples of f elements anchored by sulfur-based polydentate ligands.
DOI http://dx.doi.org/10.1021/ic0106827
ISBN
Publisher
Book Title
ISSN 0020-1669
EISSN
Conference Name
Bibtex ID ISI:000173003200003
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