Publication Type |
Journal Article |
Title |
Erbium-Doped Tin-Silicate Sol-Gel-Derived Glass-Ceramic Thin Films: Effect of Environment Segregation on the Er3+ Emission |
Authors |
Tran T. T. Van S. Turrell B. Capoen Lam Q. Vinh O. Cristini-Robbe M. Bouazaoui F. d Acapito M. Ferrari D. Ristic A. Lukowiak Rui M. Almeida L. F. Santos C. Kinowski |
Groups |
|
Journal |
SCIENCE OF ADVANCED MATERIALS |
Year |
2015 |
Month |
February |
Volume |
7 |
Number |
2 |
Pages |
301-308 |
Abstract |
A new class of glass-ceramic nanocomposite systems with a uniform distribution of SnO2 nanocrystals dispersed within an amorphous silica phase is fabricated in the form of thin films by using sol gel processing. In this work, experiments with (100-x)SiO2-xSnO(2) nanocomposite thin films with (x=25 and 30 mol\%) doped with Er3+ ions (concentrations of 0.5, 1 and 2 mol\%) are presented. The focus has been both to determine the effect of rare-earth doping on the growth of SnO2 nanocrystals as well as the distribution of the Er3+ ions within the ceramic structure. Vibrational spectroscopic assessments have proven the glass-ceramic nature of the samples. EXAFS and photoluminescence spectra show that the rare-earth ions exist in both amorphous and crystalline phases. Moreover an energy transfer from SnO2 nanocrystals to erbium ions on excitation at 351 nm is demonstrated. |
DOI |
http://dx.doi.org/10.1166/sam.2015.2022 |
ISBN |
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Publisher |
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Book Title |
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ISSN |
1947-2935 |
EISSN |
1947-2943 |
Conference Name |
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Bibtex ID |
ISI:000349140700015 |
Observations |
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