| Publication Type |
Journal Article |
| Title |
Diaquabis(N,N-diethylpyridine-3-carboxamide-kappa N-1)bis\4-[ 2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-kappa O\copper(II) |
| Authors |
Rafiqa A. Alieva Vusala I. Mardanova Famil M. Chyraqov Atash V. Gurbanov Seik Weng Ng |
| Groups |
|
| Journal |
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Year |
2012 |
| Month |
February |
| Volume |
68 |
| Number |
2 |
| Pages |
M127-U473 |
| Abstract |
In the title compound, [Cu(C12H11N2O4)(2)(C10H14N2O)(2)(H2O)(2)], the Cu-II atom lies on a center of inversion and is coordinated by carboxylate O atoms, pyridine N atoms and two water molecules in an elongated octahedral geometry. The pyridine ring is oriented at a dihedral angle of 74.83 (12)degrees with respect to the benzene ring. Intramolecular O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonding is observed. The water molecule is a hydrogen-bond donor to the carbonyl O atom of an adjacent carboxylate group, generating a chain running along the a axis. One of the ethyl groups is disordered over two sets of sites in a 0.787 (5):0.213 ratio. |
| DOI |
http://dx.doi.org/10.1107/S1600536811056200 |
| ISBN |
|
| Publisher |
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| Book Title |
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| ISSN |
1600-5368 |
| EISSN |
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| Conference Name |
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| Bibtex ID |
ISI:000301059000032 |
| Observations |
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