| Publication Type |
Journal Article |
| Title |
Reactivity and solid-state photo-luminescence of cadmium compounds constructed from 4 -Ph-terpy and cadmium salts |
| Authors |
Zhen Ma Baoqing Liu Hong Yang Yanpeng Xing Miao Hu Jianhua Sun |
| Groups |
|
| Journal |
JOURNAL OF COORDINATION CHEMISTRY |
| Year |
2009 |
| Month |
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|
| Volume |
62 |
| Number |
20 |
| Pages |
3314-3323 |
| Abstract |
Three cadmium compounds, [Cd2L2Cl(C6H5O7)]n (1), [CdLCl2] (2), and [CdL2(NO3)](NO3) center dot 2H2O (3) (L = 4 -Ph-terpy), were synthesized by hydrothermal methods from 4 -Ph-terpy and cadmium salts. The structure of 1 consists of a helical structure with cadmiums coordinated by 4 -Ph-terpy ligands and chloride and bridged by citrate, constructing a chiral 1-D polymeric compound. The cadmium in 2 is five-coordinate, bound to one tridentate terpyridine ligand and two chlorides, exhibiting a neutral mononuclear unit with an irregular CdN3Cl2 polyhedron. Compound 3 shows a seven-coordinate cadmium bound to two tridentate terpy ligands and one oxygen from nitrate in a mer configuration. The reactions producing these compounds are temperature dependent. The compounds show photo-luminescence in the solid state. |
| DOI |
http://dx.doi.org/10.1080/00958970903059992 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
0095-8972 |
| EISSN |
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| Conference Name |
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| Bibtex ID |
ISI:000269541900009 |
| Observations |
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