| Publication Type |
Journal Article |
| Title |
Sodium Nitroprusside as a Source of Metalloligand in Direct Synthesis of Cu/Fe Complexes |
| Authors |
Olesia V. Vreshch Oksana V. Nesterova Vladimir N. Kokozay Viktoriya V. Dyakonenko Oleg V. Shishkin Benoit Cormary Isabelle Malfant Julia Jezierska |
| Groups |
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| Journal |
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE |
| Year |
2009 |
| Month |
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|
| Volume |
635 |
| Number |
13 |
| Pages |
2316-2323 |
| Abstract |
This article discusses synthesis of two heterometallic complexes [Cu(phen)(2)Fe(CN)(5)(NO)]center dot 2H(2)O (1) and [Cu(phen)(3)][Fe(CN)(5)(NO)]center dot 2H(2)O (2) prepared from zerovalent copper, sodium nitroprusside (SNP), ammonium thiocyanate in dimethylformamide (DMF) solution of 1,10-phenanthroline (phen). Single crystal X-ray analysis revealed that compound 1 has a molecular structure with [Cu(phen)(2)](2+) and [Fe(CN)(5)NO](2-) blocks joined through a bridging CN group of nitroprusside whereas compound 2 consists of a separate [Cu(phen)(3)](2+) cation and [Fe(CN)(5)NO](2-) anion. The magnetic behaviour of compound I is paramagnetic. Compound 1 displays photo-induced transition to the metastable state SI after irradiation with blue light, what was proved by a low-frequency shift of nu(N-O) bands. |
| DOI |
http://dx.doi.org/10.1002/zaac.200900017 |
| ISBN |
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| Publisher |
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| Book Title |
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| ISSN |
0044-2313 |
| EISSN |
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| Conference Name |
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| Bibtex ID |
ISI:000272341200036 |
| Observations |
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