| Publication Type |
Journal Article |
| Title |
Calixarenes as High Temperature Matrices for Thermally Activated Delayed Fluorescence: C-70 in Dihomooxacalix[4]arene |
| Authors |
Tiago Palmeira Alexandre S. Miranda Paula M. Marcos Mario N. Berberan-Santos |
| Groups |
BioMol |
| Journal |
MOLECULES |
| Year |
2018 |
| Month |
March |
| Volume |
23 |
| Number |
3 |
| Pages |
|
| Abstract |
Thermally activated delayed fluorescence (TADF) of C-12(70) and C-13(70) was observed up to 140 degrees C in a p-tert-butyldihomooxacalix[4]arene solid matrix, a temperature range significantly higher than that of previous TADF quantitative studies. An effective singlet-triplet energy gap of 29 kJ/mol and triplet formation quantum yields of 0.97 and 0.99 were measured for C-12(70) and C-13(70), respectively. The photophysical properties of the two fullerenes in this new matrix are comparable to those obtained in polystyrene at a lower temperature range. Calixarenes are proposed to be suitable matrices for high temperature TADF studies and applications. |
| DOI |
http://dx.doi.org/10.3390/molecules23030558 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
1420-3049 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000428514100049 |
| Observations |
|
