| Publication Type |
Journal Article |
| Title |
Reverse Arene Sandwich Structures Based upon -Hole[M-II] (d(8)M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile |
| Authors |
Anton V. Rozhkov Mariya A. Krykova Daniil M. Ivanov Alexander S. Novikov Anna A. Sinelshchikova Marina V. Volostnykh Mikhail A. Konovalov Mikhail S. Grigoriev Yulia G. Gorbunova V. Yu. Kukushkin |
| Groups |
CCC |
| Journal |
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION |
| Year |
2019 |
| Month |
March |
| Volume |
58 |
| Number |
13 |
| Pages |
4164-4168 |
| Abstract |
The complexes [Pt(tpp)] (H(2)tpp=tetraphenylporphyrin), [M(acac)(2)] (M=Pd, Pt, Hacac=acetylacetone), and [Pd(ba)(2)] (Hba=benzoylacetone) were co-crystallized with highly electron-deficient arene systems to form reverse arene sandwich structures built by -hole[M-II] (d(8)M=Pt, Pd) interactions. The adduct [Pt(tpp)]2C(6)F(6) is monomeric, whereas the diketonate 1:1 adducts form columnar infinity 1D-stack assembled by simultaneous action of both -hole[M-II] and CF interactions. The reverse sandwiches are based on noncovalent interactions and calculated ESP distributions indicate that in -hole[M-II] contacts, [M-II] plays the role of a nucleophile. |
| DOI |
http://dx.doi.org/10.1002/anie.201814062 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
1433-7851 |
| EISSN |
1521-3773 |
| Conference Name |
|
| Bibtex ID |
ISI:000462655400008 |
| Observations |
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