| Abstract |
Reaction of the o-[(o-hydroxyphenyl)methylideneamino]benzenesulfonic acid (H2L) (1) with CuCl2 center dot 2H(2)O in the presence of pyridine (py) leads to [Cu(L)(py)(EtOH)] (2) which, upon further reaction with 2,2 -bipyridine (bipy), pyrazine (pyr), or piperazine (pip), forms [Cu(L)(bipy)]center dot MeOH (3), [Cu-2(L)(2)(mu-pyr)(MeOH)(2)] (4), or [Cu-2(L)(2)(mu-pip)(MeOH)(2)] (5), respectively. The Schiff base (1) and the metal complexes (2-5) are stabilized by a number of non-covalent interactions to form interesting H-bonded multidimensional polymeric networks (except 3), such as zigzag 1D chain (in 1), linear 1D chain (in 2), hacksaw double chain 1D (in 4) and 2D motifs (in 5). These copper(II) complexes (2-5) catalyze the peroxidative oxidation of cyclic hydrocarbons (cyclooctane, cyclohexane, and cyclohexene) to the corresponding products (alcohol and ketone from alkane; alcohols, ketone, and epoxide from alkene), under mild conditions. For the oxidation of cyclooctane with hydrogen peroxide as oxidant, used as a model reaction, the best yields were generally achieved for complex 3 in the absence of any promoter (20\%) or in the presence of py or HNO3 (26\% or 30\%, respectively), whereas 2 displayed the highest catalytic activity in the presence of HNO3 (35\%). While the catalytic reactions were significantly faster with py, the best product yields were achieved with the acidic additive. |
