| Publication Type |
Journal Article |
| Title |
Redox-Neutral Ru(0)-Catalyzed Alkenylation of 2-Carboxaldimine-heterocyclopentadienes br |
| Authors |
Roberto Sala Gredy Kiala Luis F. Veiros Gianluigi Broggini Giovanni Poli Julie Oble |
| Groups |
IOARC |
| Journal |
JOURNAL OF ORGANIC CHEMISTRY |
| Year |
2022 |
| Month |
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|
| Volume |
87 |
| Number |
7 |
| Pages |
4640-4648 |
| Abstract |
A new Ru3(CO)12-catalyzed directed alkenylation of2-carboxaldimine-heterocyclopentadienes has been accomplished.This process allows coupling of furan, pyrrole, indole, andthiophene 2-carboxaldimines with electron-poor alkenes such asacrylates, vinylsulfones, and styrenes. This regio- and chemo-selective oxidative C-H coupling does not require the presence ofan additional sacrificial oxidant. Density functional theory calculations allowed us to propose a mechanism and unveiled the nature ofthe H2acceptor. |
| DOI |
http://dx.doi.org/10.1021/acs.joc.1c03044 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
0022-3263 |
| EISSN |
1520-6904 |
| Conference Name |
|
| Bibtex ID |
WOS:000784116400014 |
| Observations |
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