Publication Type Journal Article
Title An infinite two-dimensional hybrid water-chloride network, self-assembled in a hydrophobic terpyridine iron(II) matrix
Authors Ricardo R. Fernandes A Kirillov M. Fátima C. Guedes da Silva Zhen Ma J A L Silva J.J.R. Fraústo da Silva Armando J.L. Pombeiro
Groups BioMol CCC BIOIN
Journal CRYSTAL GROWTH \& DESIGN
Year 2008
Month March
Volume 8
Number 3
Pages 782-785
Abstract An unprecedented two-dimensional water-chloride anionic \[(H2O)(20)(Cl)(4)](4-)\n network has been structurally identified in a hydrophobic matrix of the iron(II) compound [FeL2]Cl-2 center dot 10H(2)O (L = 4 -phenyl-2,2 :6 ,2 -terpyridine). Its intricate relief geometry has been described as a set of 10 nonequivalent alternating cycles of different sizes ranging from tetra- to octanuclear \[(H2O)(x)(Cl)(y)](y-)\(z) (x = 2-6, y = 0-2, z = 4-6, 8) fragments.
DOI http://dx.doi.org/10.1021/cg7010315
ISBN
Publisher AMER CHEMICAL SOC
Book Title
ISSN 1528-7483
EISSN
Conference Name
Bibtex ID ISI:000253800200009
Observations
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