| Publication Type |
Journal Article |
| Title |
Solvent-free microwave-assisted peroxidative oxidation of secondary alcohols to the corresponding ketones catalyzed by copper(II) 2,4-alkoxy-1,3,5-triazapentadienato complexes |
| Authors |
Pawel J. Figiel Maximilian N. Kopylovich Jamal Lasri M. Fátima C. Guedes da Silva J.J.R. Fraústo da Silva Armando J.L. Pombeiro |
| Groups |
CCC |
| Journal |
CHEMICAL COMMUNICATIONS |
| Year |
2010 |
| Month |
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|
| Volume |
46 |
| Number |
16 |
| Pages |
2766-2768 |
| Abstract |
A facile, efficient and selective solvent-free synthesis of ketones from secondary alcohols with tert-butylhydroperoxide (TBHP) as the oxidant under microwave irradiation is achieved, where the copper(II) 2,4-alkoxy-1,3,5-triazapentadienato complexes are efficient catalysts providing high yields (up to 100\%), TONs (up to 890) and TOFs (up to 1780 h(-1)). |
| DOI |
http://dx.doi.org/10.1039/b922738e |
| ISBN |
|
| Publisher |
ROYAL SOC CHEMISTRY |
| Book Title |
|
| ISSN |
1359-7345 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000276376000014 |
| Observations |
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