Publication Type Journal Article
Title Cyanoimide-Bridged, Bi- and Trinuclear, Heterometallic Complexes with an NCN-Mo-NCN Phosphinic Core
Authors Sonia M. P. R. M. Cunha M. Fátima C. Guedes da Silva J.J.R. Fraústo da Silva Armando J.L. Pombeiro
Groups CCC
Journal EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Year 2009
Month September
Volume
Number 26
Pages 3966-3971
Abstract The heterometallic dinuclear complexes of the types trans[Mo(NCN)(dppe)2(mu the corresponding transition-metal Lewis acid (M) precursors, particularly [VCl3(thf)(3)], [WCl4(PPh3)(2)], [ReOCl3(PPh3)2], trans-[ReCl(N-2) (PMePh2)4], trans-[FeBr(NCC(6)H(4)NO(2)4)(depe)(2)][BF4] and [Pt2Cl4(PEt3)(2)]. These adducts were characterized by FTIR, H-1, C-13 and P-31\H-1\) NMR spectroscopy, mass spectrometry and cyclic voltammetry. ((C) Wiley-VCH Verlag GmbH \& Co. KGaA, 69451 Weinheim, Germany, 2009)-NCN)MJ [M = WCl4(PPh3), ReOCl3(PPh3) or mer-ReCl(N-2)(PMePh2)(3); dppe = Ph2PCH2CH2PPh2] and [Mo(NCN)(dppe)(2)(mu-NCN)MJ[I3F4]Br IM = transFe(NCC(6)H(4)NO2-4)(depe)2; depe = Et(2)PCH(2)CH(2)PEt(2)J and the trinuclear ones [Mo(dppe)2Rp-NCN)M)21 [M = VCl3(thf) or PtCl2(PEt3)] were prepared by reaction of the bis(cyanomudo)molybdenum complex trans- [Mo(NCN)(2)(dppe)(2)] with
DOI http://dx.doi.org/10.1002/ejic.200900398
ISBN
Publisher WILEY-V C H VERLAG GMBH
Book Title
ISSN 1434-1948
EISSN
Conference Name
Bibtex ID ISI:000270014500013
Observations
Back to Publications List