Publication Type Journal Article
Title Aerosol-assisted metallo-organic chemical vapour deposition of Bi2Se3 films using single-molecule precursors. The crystal structure of bismuth(III) dibutyldiselenocarbamate
Authors O. Monteiro T Trindade FAA Paz J Klinowski J Waters P O Brien
Groups
Journal JOURNAL OF MATERIALS CHEMISTRY
Year 2003
Month
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Volume 13
Number 12
Pages 3006-3010
Abstract The complexes [Bi\Se2CN(C2H5)(2)\(3)], [Bi\Se2CN(C4H9)(2)\(3)], [Bi\Se2CN(CH3)(C4H9)\(3)] and [Bi\Se2CN(CH3)(C6H13)\(3)] have been synthesized and characterized structurally using IR, H-1 and C-13 NMR. In addition, the crystal structure of [Bi\Se2CN(C4H9)(2)\(3)] was determined by single-crystal X-ray diffraction, showing the bismuth centre coordinated to three dialkyldiselenocarbamate ligands through the selenium donor atoms. The Bi(III) compounds were used as precursors for the deposition of Bi2Se3 films on glass substrates through aerosol-assisted metallo-organic chemical vapour deposition (AA-MOCVD).
DOI http://dx.doi.org/10.1039/b306662m
ISBN
Publisher
Book Title
ISSN 0959-9428
EISSN
Conference Name
Bibtex ID ISI:000186907500035
Observations
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