| Abstract |
A series of water-soluble metal formazanates, [Al-2(OH)(2)(H2O)(8)](HL)(2) (1), [\Fe(H2O)(4)\(HL)(H2L)]center dot 2H(2)O (2) and [Cu(en)(2)(H2O)(2)][CuL(H2O)(2)](2) (3), were synthesized by the reaction of sodium 2-(2-((E)-cyano((E)-(2-sulfonatophenyl)diazenyl)methylene)hydrazineyl) benzenesulfonate (Na2HL) with Al(NO3)(3)center dot 9H(2)O, FeCl3 center dot 6H(2)O and Cu(NO3)(2)center dot 3H(2)O (in the presence of ethylenediamine) in methanol, respectively. The formazan pro-ligand Na2HL and its complexes 1-3 were characterized by ESI-MS, H-1/C-13 NMR (for Na2HL), IR spectroscopy, elemental and X-ray diffraction analyses (for 1-3). According to the X-ray analysis, the formazanate behaves as an anion or displays a mono- or bidentate coordination mode, for the Al, Fe or Cu centre, respectively. All complexes were tested as catalysts for the peroxidative (with H2O2) oxidation of cyclohexane and cyclohexanol to the coresponding organic products at room temperature. The complexes 2 and 3 are active homogeneous catalysts for the microwave-assisted peroxidative oxidation with aqueous H2O2 of cyclohexane (to cyclohexanol and cyclohexanone) and cyclohexanol to cyclohexanone. |
