Publication Type Journal Article
Title Enhancing SIM behaviour in a mononuclear tetrahedral [Co(N,N -2-iminopyrrolyl)(2)] complex
Authors Patrícia S. Ferreira Jose F. Malta Nuno A. G. Bandeira Alexander Allgaier Joris van Slageren Jose A. Paixao Manuel Almeida Laura C. J. Pereira Pedro T. Gomes
Groups IOARC
Journal CHEMICAL COMMUNICATIONS
Year 2022
Month
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Volume 58
Number 69
Pages 9682-9685
Abstract A new homoleptic Co(ii) complex bearing two highly sterically congested 2-formiminopyrrolyl N,N -chelating ligands is reported, displaying slow relaxation of the magnetisation at zero static (DC) field. This compound shows a large value for the zero-field splitting (ZFS) parameter D of -42.6(4) cm(-1) leading to a spin-reversal energy barrier U-eff of 85 cm(-1).
DOI http://dx.doi.org/10.1039/d2cc03511a
ISBN
Publisher ROYAL SOC CHEMISTRY
Book Title
ISSN 1359-7345
EISSN 1364-548X
Conference Name
Bibtex ID WOS:000838569000001
Observations
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