Publication Type |
Journal Article |
Title |
Enhancing SIM behaviour in a mononuclear tetrahedral [Co(N,N -2-iminopyrrolyl)(2)] complex |
Authors |
Patrícia S. Ferreira Jose F. Malta Nuno A. G. Bandeira Alexander Allgaier Joris van Slageren Jose A. Paixao Manuel Almeida Laura C. J. Pereira Pedro T. Gomes |
Groups |
IOARC |
Journal |
CHEMICAL COMMUNICATIONS |
Year |
2022 |
Month |
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|
Volume |
58 |
Number |
69 |
Pages |
9682-9685 |
Abstract |
A new homoleptic Co(ii) complex bearing two highly sterically congested 2-formiminopyrrolyl N,N -chelating ligands is reported, displaying slow relaxation of the magnetisation at zero static (DC) field. This compound shows a large value for the zero-field splitting (ZFS) parameter D of -42.6(4) cm(-1) leading to a spin-reversal energy barrier U-eff of 85 cm(-1). |
DOI |
http://dx.doi.org/10.1039/d2cc03511a |
ISBN |
|
Publisher |
ROYAL SOC CHEMISTRY |
Book Title |
|
ISSN |
1359-7345 |
EISSN |
1364-548X |
Conference Name |
|
Bibtex ID |
WOS:000838569000001 |
Observations |
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