| Publication Type |
Journal Article |
| Title |
Addition of N-nucleophiles to gold(III)-bound isocyanides leading to short-lived gold(III) acyclic diaminocarbene complexes |
| Authors |
Tatyana B. Anisimova Mikhail A. Kinzhalov M. Fátima C. Guedes da Silva Alexander S. Novikov V. Yu. Kukushkin Armando J.L. Pombeiro K. Luzyanin |
| Groups |
CCC |
| Journal |
NEW JOURNAL OF CHEMISTRY |
| Year |
2017 |
| Month |
May |
| Volume |
41 |
| Number |
9 |
| Pages |
3246-3250 |
| Abstract |
Reaction of [AuCl3(CNR1)] (R-1 = Xyl, Cy, (S)-CHMePh) with amines unexpectedly proceeds via the redox pathway giving gold(I)-isocyanides and imines, while the addition of benzophenone hydrazone to the isocyanide ligand in [AuCl3(CNR1)] at RT leads to short-lived gold(III) acyclic diaminocarbene complexes [AuCl3\C(NHNCPh2)NHR1\]. |
| DOI |
http://dx.doi.org/10.1039/c7nj00529f |
| ISBN |
|
| Publisher |
ROYAL SOC CHEMISTRY |
| Book Title |
|
| ISSN |
1144-0546 |
| EISSN |
1369-9261 |
| Conference Name |
|
| Bibtex ID |
ISI:000401530500003 |
| Observations |
|
