| Publication Type |
Journal Article |
| Title |
Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones |
| Authors |
Carmen A. Montoya Clara F. Gomez Ana B. Paninho Ana Nunes Kamran T. Mahmudov Vesna Najdanovic-Visak L.M.D.R.S. Martins M. Fátima C. Guedes da Silva Armando J.L. Pombeiro Manuel Nunes da Ponte |
| Groups |
CCC |
| Journal |
JOURNAL OF CATALYSIS |
| Year |
2016 |
| Month |
March |
| Volume |
335 |
| Number |
|
| Pages |
135-140 |
| Abstract |
Zinc(II) complexes of arylhydrazones of beta-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity. (C) 2016 Elsevier Inc. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/j.jcat.2015.12.027 |
| ISBN |
|
| Publisher |
ACADEMIC PRESS INC ELSEVIER SCIENCE |
| Book Title |
|
| ISSN |
0021-9517 |
| EISSN |
1090-2694 |
| Conference Name |
|
| Bibtex ID |
ISI:000371098200013 |
| Observations |
|
