| Publication Type |
Journal Article |
| Title |
trans-Bis[5-(4-fluorophenyl)tetrazolato]bis(triphenylphosphine)platinu m(II) |
| Authors |
Suman Mukhopadhyay Jamal Lasri M. Fátima C. Guedes da Silva Adilia Charmier Armando J.L. Pombeiro |
| Groups |
CCC |
| Journal |
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Year |
2007 |
| Month |
November |
| Volume |
63 |
| Number |
11 |
| Pages |
M2656-U281 |
| Abstract |
The diazide platinum(II) complex, [Pt(N-3)(2)(PPh3)(2)], reacts with 4-FC6H4CN under microwave irradiation to give the corresponding neutral title bis(tetrazolate) complex trans[Pt(N4CR)(2)(PPh3)(2)] or [Pt(C7H4FN4)(2)(C18H15P)(2)]. The Pt-II atom lies on a crystallographic inversion centre and is coordinated by two N atoms and two P atoms in a slightly distorted square-planar environment. The unique tetrazolate ring is essentially planar and the corresponding C - N and N - N bond distances lie in the range 1.317 (3)-1.349 (3) angstrom. |
| DOI |
http://dx.doi.org/10.1107/S1600536807047617 |
| ISBN |
|
| Publisher |
WILEY-BLACKWELL |
| Book Title |
|
| ISSN |
1600-5368 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000251281800027 |
| Observations |
|
