Publication Type Journal Article
Title Hollow Co0.85Se Nanowire Array on Carbon Fiber Paper for High Rate Pseudocapacitor
Authors Abhik Banerjee Sumit Bhatnagar Kush Kumar Upadhyay Prasad Yadav Satishchandra Ogale
Groups
Journal ACS APPLIED MATERIALS \& INTERFACES
Year 2014
Month November
Volume 6
Number 21
Pages 18844-18852
Abstract A supercapacitor electrode is fabricated with Co0.85Se hollow nanowires (HNW) array, which is synthesized by wet chemical hydrothermal selenization of initially grown cobalt hydroxyl carbonate nanowires on conductive CFP. The dense self-organized morphology of Co0.85Se HNWs is revealed by scanning/transmission electron microscopy. The as-synthesized Co0.85Se HNWs possess high pseudocapacitive property with high capacitance retention and high durability. The areal capacitance value is seen to vary from 929.5 to 600 mF cm(-2) (60\% retention) as the current density is increased from 1 to 15 mA cm(-2), an increase of a factor of 15. Based on mass loading, this corresponds to a very high gravimetric capacitance of 674 (for 2 mA cm(-2) or 1.48 Ag-1) and 444 Fg(1-) (for 15 mA cm(-2) or 11 A g(-1)) in a full-cell configuration with the Co0.85Se HNWs as cathode and activated carbon as anode (asymmetric configuration) promising results are obtained.
DOI http://dx.doi.org/10.1021/am504333z
ISBN
Publisher
Book Title
ISSN 1944-8244
EISSN
Conference Name
Bibtex ID ISI:000344978200061
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