Publication Type Journal Article
Title Solid-supported nitrogen acyclic carbene (SNAC) complexes of gold: Preparation and catalytic activity
Authors Svetlana Tsupova Alban Cadu Sónia A.C. Carabineiro Matthias Rudolph A. S. K. Hashmi
Groups
Journal JOURNAL OF CATALYSIS
Year 2017
Month June
Volume 350
Number
Pages 97-102
Abstract A readily accessible route to obtain solid-supported nitrogen acyclic carbene (SNAC) complexes of gold was designed using flow chemistry, and an analogous homogeneous gold complex was synthesized for comparison. Both were screened for counter ions in order to perform the Hashmi phenol synthesis. A recyclability study was performed on the SNAC complex, which showed the high stability of this catalyst, with no observed leaching or gold nanoparticle formation. XPS analysis was employed to confirm the presence of gold and its oxidation state. (C) 2017 Elsevier Inc. All rights reserved.
DOI http://dx.doi.org/10.1016/j.jcat.2017.03.013
ISBN
Publisher
Book Title
ISSN 0021-9517
EISSN 1090-2694
Conference Name
Bibtex ID ISI:000402351800011
Observations
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