Publication Type |
Journal Article |
Title |
Halogen bonding between metal centers and halocarbons |
Authors |
Daniil M. Ivanov Alexander S. Novikov Ivan V. Ananyev Yulia V. Kirina V. Yu. Kukushkin |
Groups |
|
Journal |
CHEMICAL COMMUNICATIONS |
Year |
2016 |
Month |
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|
Volume |
52 |
Number |
32 |
Pages |
5565-5568 |
Abstract |
Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk(2))(2)] (X = Cl, Br). The HI2C-I center dot center dot center dot eta(1)((Pt)) halogen bonding and the bifurcated HI2C-I center dot center dot center dot eta(2)((Pt-Cl)) halogen bonding - the latter undergoes the thermally induced reversible HI2C-I center dot center dot center dot eta(2)((Pt-Cl)) reversible arrow HI2C-I center dot center dot center dot eta(1)((Pt)) transformation - were observed and confirmed theoretically. |
DOI |
http://dx.doi.org/10.1039/c6cc01107a |
ISBN |
|
Publisher |
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Book Title |
|
ISSN |
1359-7345 |
EISSN |
1364-548X |
Conference Name |
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Bibtex ID |
ISI:000374035800015 |
Observations |
|