| Abstract |
This paper reports on the study of the effects of silver (Ag degrees) nanoparticles on the optical and spectroscopic properties of Er3+-doped silica-based gels and glasses.. including active bulk materials and planar waveguides for integrated optics. Two different procedures for silver and erbium ion incorporation into the glassy matrices have been investigated: the direct incorporation of a metal salt (AgNO3 and/or Er(NO3)(3)) into the sol-gel solution, as well as a modified sol-gel process, based on pore-doping of a precursor gel with AgNO3 and/or Er(NO3)(3) solutions. The study of the parameters determining the average size and size distribution of the nanoparticles, together with their influence on the sol-gel material densification and Er3+ photoluminescence at 1.5 pm, has been performed by means of transmission electron microscopy, plus ultra-violet/visible and photoluminescence spectroscopies. The Ag degrees colloidal nanoparticles, obtained by thermal precipitation, were approximately spherical, homogeneously distributed and they exhibited an average size between similar to 2 and 15 nm, depending on the silver content and heat treatment performed. They are shown to be responsible for a remarkable enhancement of the Er3+ photoluminescence intensity, which is mainly due to the increase of the local electric field around the Er3+ ions, due to the surface plasmon resonance of the Ag degrees nanoparticles. (c) 2007 Published by Elsevier B.V. |
