Publication Type |
Journal Article |
Title |
Structural and magnetic properties of P25 TiO2 nanoparticles doped by Co |
Authors |
Jose F. M. L. Mariano Valentim G. Bessergenev João P. Lourenço Martin Hantusch Eberhard Burkel Ana M. Botelho do Rego Michal Rajnak Milan Timko Peter Kopcansky |
Groups |
Chem4Env |
Journal |
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS |
Year |
2020 |
Month |
May |
Volume |
501 |
Number |
|
Pages |
|
Abstract |
The present work reports on the structural and magnetic properties of TiO2 P25 Degussa powder doped with cobalt. Dissolution of cobalt in TiO2 matrix was achieved by precipitation of tris(diethyldithiocarbamato) cobalt (III) (CoDtc - Co[S2CN(C2H5)(2)](3) in chloroform (CHCl3) and consequent thermal treatment. Five different Co atomic percentage contents were chosen, e.g., 0.5\%, 1\%, 2\%, 5\% and 10\%. It was shown that cobalt atoms are uniformly distributed across TiO2 matrix and exhibit antiferromagnetic interactions at low temperatures. |
DOI |
http://dx.doi.org/10.1016/j.jmmm.2020.166442 |
ISBN |
|
Publisher |
|
Book Title |
|
ISSN |
0304-8853 |
EISSN |
1873-4766 |
Conference Name |
|
Bibtex ID |
ISI:000513901000013 |
Observations |
|