| Publication Type |
Journal Article |
| Title |
Cycloaddition reactions of nitrosoalkenes, azoalkenes and nitrile oxides mediated by hydrotalcite |
| Authors |
Americo Lemos João P. Lourenço |
| Groups |
Chem4Env |
| Journal |
ARKIVOC |
| Year |
2010 |
| Month |
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|
| Volume |
|
| Number |
5 |
| Pages |
170-182 |
| Abstract |
Mg:Al 3:1 hydrotalcite (Ht), used in catalytic quantities, promotes the generation of nitrosoalkenes, azoalkenes and nitrile oxides. These can be intercepted in situ by heterocycles and olefins in [4+2] and [3+2] cycloaddition reactions, producing dihydro-1,2-oxazines, tetrahydropyridazines and isoxazolines. The regeneration and reuse of Ht without loss of activity and the absence of organic solvent are the main advantages of this methodology. |
| DOI |
http://dx.doi.org/10.3998/ark.5550190.0011.515 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
1551-7004 |
| EISSN |
1551-7012 |
| Conference Name |
|
| Bibtex ID |
WOS:000280583300015 |
| Observations |
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