| Publication Type |
Journal Article |
| Title |
A picolinate-N-2 complex of rhenium, the first dinitrogen complex bearing a carboxylate or a N,O-ligand |
| Authors |
A Kirillov Matti Haukka M. Fátima C. Guedes da Silva J.J.R. Fraústo da Silva Armando J.L. Pombeiro |
| Groups |
BioMol CCC |
| Journal |
JOURNAL OF ORGANOMETALLIC CHEMISTRY |
| Year |
2006 |
| Month |
September |
| Volume |
691 |
| Number |
19 |
| Pages |
4153-4158 |
| Abstract |
A new dinitrogen rhenium(I) complex with a picolinate ligand has been prepared and fully characterized, providing the first example of a genuine N N complex bearing a carboxylate or a N,O-coligand. The Lever electrochemical E-L ligand parameter was estimated for the first time for the picolinate ligand and shows that its carboxylate arm has a net electron-donor character similar to that of chloride, thus stabilizing the trans Re-N-2 bond. (c) 2006 Elsevier B.V. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/j.jorganchem.2006.06.015 |
| ISBN |
|
| Publisher |
ELSEVIER SCIENCE SA |
| Book Title |
|
| ISSN |
0022-328X |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000240809700025 |
| Observations |
|
