Publication Type |
Journal Article |
Title |
A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst |
Authors |
Manas Sutradhar M Kirillova M. Fátima C. Guedes da Silva L.M.D.R.S. Martins Armando J.L. Pombeiro |
Groups |
CCC BioMol |
Journal |
INORGANIC CHEMISTRY |
Year |
2012 |
Month |
November |
Volume |
51 |
Number |
21 |
Pages |
11229-11231 |
Abstract |
The new hexanuclear mixed-valence vanadium complex [V3O3(OEt)(ashz)(2)(mu-OEt)](2) (1) with an N,O-donor ligand is reported. It acts as a highly efficient catalyst toward alkane oxidations by aqueous H2O2. Remarkably, high turnover numbers up to 25000 with product yields of up to 27\% (based on alkane) stand for one of the most active systems for such reactions. |
DOI |
http://dx.doi.org/10.1021/ic3017062 |
ISBN |
|
Publisher |
|
Book Title |
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ISSN |
0020-1669 |
EISSN |
|
Conference Name |
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Bibtex ID |
ISI:000313220200007 |
Observations |
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