| Publication Type |
Journal Article |
| Title |
Thermodynamics of liquid mixtures of xenon with Alkanes: (xenon plus n-butane) and (xenon plus isobutane) |
| Authors |
Eduardo J. M. Filipe LFG Martins J. Calado Clare McCabe G. Jackson |
| Groups |
MET FM |
| Journal |
JOURNAL OF PHYSICAL CHEMISTRY B |
| Year |
2000 |
| Month |
February |
| Volume |
104 |
| Number |
6 |
| Pages |
1322-1325 |
| Abstract |
The total vapor pressure of liquid mixtures of (xenon + n-butane) has been measured at 182.34 and 195.49 K, and of (xenon + isobutane) at 195.49 K. The liquid: molar volumes have also been measured at 182.34 K for both systems. The mixtures follow the behavior already found for other (xenon + alkane) mixtures, i.e., negative deviations from Raoult s law, negative excess molar Gibbs energies (G(m)(E)) and negative excess molar volumes (V-m(E)). The excess molar enthalpy (H-m(E)) is approximately zero in the case of (xenon + n-butane). The results were interpreted using the statistical association fluid theory for potentials of variable attractive range (SAFT-VR). This study provides further evidence that the (xenon + n-alkane) mixtures can be thought of as a particular case of mixtures of n-alkanes. |
| DOI |
http://dx.doi.org/10.1021/jp992801y |
| ISBN |
|
| Publisher |
AMER CHEMICAL SOC |
| Book Title |
|
| ISSN |
1089-5647 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000085393900026 |
| Observations |
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