| Publication Type |
Journal Article |
| Title |
The first direct observation of N-O bond cleavage in the oxidative addition of an oxime to a metal centre. Synthesis and crystal structure of the methyleneamide complex trans-[Re(OH)(N=CMe2)(Ph2PCH2CH2PPh2)(2)][HSO4] |
| Authors |
CMP Ferreira M. Fátima C. Guedes da Silva V. Yu. Kukushkin J.J.R. Fraústo da Silva Armando J.L. Pombeiro |
| Groups |
|
| Journal |
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS |
| Year |
1998 |
| Month |
February |
| Volume |
|
| Number |
3 |
| Pages |
325-326 |
| Abstract |
The first direct observation of oxidative addition of an oxime upon N-O bond cleavage has been reported in the reaction of Me2C=NOH with trans-[ReCl(N-2)(Ph2PCH2CH2PPh2)(2)] in the presence of Tl[BF4]-Tl[HSO4], to form, in a single-pot experiment, the methyleneamide complexes trans-[Re(OH)(N=CMe2)(dppe)(2)][A] (A = BF4 1a or HSO4 1b) which undergo ready replacement of hydroxide by fluoride upon reaction with HBF4; X-ray crystallography (1b) showed that the linearly bound methyleneamide behaves as an effective pi acceptor and exerts a significant trans influence on the hydroxide ligand. |
| DOI |
http://dx.doi.org/10.1039/a707213i |
| ISBN |
|
| Publisher |
ROYAL SOC CHEMISTRY |
| Book Title |
|
| ISSN |
1472-7773 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000072111100003 |
| Observations |
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