| Publication Type |
Journal Article |
| Title |
Formation of vinyl and dithioformate metallacycles by insertion of an ester-functionalized alkyne or carbon disulfide into an Fe-H bond: Crystal structure of cis-[Fe(CH=CHCOOMe)(Ph(2)PCH(2)CH(2)PPh(2))(2)][BF4] |
| Authors |
SSP Almeida M. Teresa Duarte LMD Ribeiro F Gormley Adelino M. Galvão J.J.R. Fraústo da Silva Armando J.L. Pombeiro |
| Groups |
|
| Journal |
JOURNAL OF ORGANOMETALLIC CHEMISTRY |
| Year |
1996 |
| Month |
November |
| Volume |
524 |
| Number |
1 |
| Pages |
63-66 |
| Abstract |
Treatment of a THF solution of trans-[FeHCl(dppe)(2)] (dppe = Ph(2)PCH(2)CH(2)PPh(2)) with HC=CCOOMe or CS2, in the presence of Tl[BF4], forms the vinyl complex cis-[Fe(CH = CHCOOMe)(dppe)(2)][BF4] or the eta(2)-dithioformate compound cis-[Fe(eta(2)-S2CH)(dppe)(2)][BF4] respectively. The molecular structure of the former is authenticated by X-ray diffraction analysis. |
| DOI |
http://dx.doi.org/10.1016/S0022-328X(96)06290-0 |
| ISBN |
|
| Publisher |
ELSEVIER SCIENCE SA |
| Book Title |
|
| ISSN |
0022-328X |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:A1996VZ15200007 |
| Observations |
|
