Publication Type |
Journal Article |
Title |
Mononuclear and tetranuclear Fe(III) complexes with two different types of N, O donor Schiff base ligands |
Authors |
Manas Sutradhar Tannistha Roy Barman Michael G. B. Drew Eva Rentschler |
Groups |
|
Journal |
JOURNAL OF MOLECULAR STRUCTURE |
Year |
2013 |
Month |
June |
Volume |
1041 |
Number |
|
Pages |
44-49 |
Abstract |
A mononuclear Fe(III) complex of a tetradentate N2O2 donor Schiff base ligand derived from 3-ethoxysalicaldehyde and ethylenediamine has been reported. In addition two tetranuclear Fe(III) complexes with discrete Fe-4(III)(mu(4)-0) cores have been synthesized and characterized using two Schiff base ligands (H2L1-2) derived from two different aromatic acid hydrazides and diacetyl monoxime. The mononuclear Fe(III) and one of the tetranuclear Fe(III) complexes have been structurally characterized by single-crystal X-ray crystallography. The mononuclear complex has a highly distorted octahedral geometry. The tetranuclear Fe(III) complexes are found to be rare examples with discrete neutral alkoxido-oxido clusters with Fe-4(III)(mu(4)-0) cores. (C) 2013 Elsevier B.V. All rights reserved. |
DOI |
http://dx.doi.org/10.1016/j.molstruc.2013.02.035 |
ISBN |
|
Publisher |
|
Book Title |
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ISSN |
0022-2860 |
EISSN |
|
Conference Name |
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Bibtex ID |
ISI:000319176700007 |
Observations |
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